Density of neutral solitons in weakly disordered Peierls chains.
(1998) Density of neutral solitons in weakly disordered Peierls chains. Physical Review B 57(5), 2861-2871.
We study the effects of weak off-diagonal disorder on Peierls systems with a doubly degenerate ground state. We show that for these systems disorder in the electron hopping amplitudes induces a finitedensity ofsolitons in the minimal-energy lattice configuration of a single chain. These disorder-induced dimerization kinks are neutral and have spin 1/2. Using a continuum model for the Peierls chain and treating the lattice classically, we analytically calculate the average free energy and density of kinks. We compare these results to numerical calculations for a discrete model and discuss the implications of the kinks for theoptical and magnetic properties of the conjugated polymer trans-polyacetylene.